Anti-frizz Spray Apple Vinegar It contains a series of actives that provide thermal protection with a smooth texture. The main one is Apple Cider Vinegar, which is a powerful regulator of the pH of the hair cuticle, keeping it sealed, thus reducing the porous appearance of the hair and ensuring an explosion of shine. It also contains Grape Seed Oil which is rich in vitamin E which has antioxidant properties in addition to leaving the hair extremely soft and hydrated.